Lanthanide cation-templated synthesis of rotaxanes.
نویسندگان
چکیده
The first lanthanide cation-templated synthesis of an interlocked structure is demonstrated through an interpenetrated assembly between a pyridine N-oxide threading component coordinating to a lanthanide cation complexed within a macrocycle. Stoppering of the pseudo-rotaxane assembly allows for preparation of the [2]rotaxane.
منابع مشابه
Nitrite-Templated Synthesis of Lanthanide-Containing [2]Rotaxanes for Anion Sensing**
The first anion-templated synthesis of a lanthanide-containing interlocked molecule is demonstrated by utilizing a nitrite anion to template initial pseudorotaxane formation. Subsequent stoppering of the interpenetrated assembly allows for the preparation of a lanthanide-functionalized [2]rotaxane in high yield. Following removal of the nitrite anion template, the europium [2]rotaxane host is d...
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 74 شماره
صفحات -
تاریخ انتشار 2013